Of course it is possible
You probably mean something like this.
Such things are normally done with Excel VBA, not VB6
You should probably post in the "VBA / Office Integration > Excel
section of the forum to get the appropriate vba code.
I can give you a hint before you head over there...
How can I explode a piece of a pie chart and
write inside a piece of a pie chart?
For others who may want answers to these questions and need a
a sample "of drawing a pie chart with selectable exploding slice"
appropriate to this
"Legacy Visual Basic (VB 4/5/6) > Interface and Graphics" forum,
I have attached a demo with screenshot below.
If you want a 3D like pie chart an/or allow it to be tilt-able
as well as rotate-able you should check out the code here